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• W2027657613 abstract "We present a finite chain-length calculation of the rubber elasticity of an isotropic crosslinked network of freely jointed chains under affine deformation. Whilst this is a classical calculation, the result is derived in its full tensorial structure for the first time, and new predictions of non-Gaussian elasticity for general biaxial deformations are presented. The full tensorial rubber-elasticity derivation allows any deformation regime to be treated, to facilitate validation with experimental data. Even though more complex many-chain effects are neglected, this theory appears to be the only one to offer a physical explanation for negative values of W2 observed experimentally at small strains." @default.
• W2027657613 created "2016-06-24" @default.
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• W2027657613 date "1999-03-01" @default.
• W2027657613 modified "2023-09-25" @default.
• W2027657613 title "Finite chain-length effects in rubber elasticity" @default.
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• W2027657613 doi "https://doi.org/10.1016/s0032-3861(98)00272-9" @default.
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