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- W2027675974 abstract "Abstract The passivation and breakdown behavior of 304 stainless steel in propylene carbonate (PC) or dimethoxyethane (DME) mixtures with water and containing 0.5 M LiAsF 6 were studied. The air-formed film of 304 stainless steel provides a good passive film that resists breakdown. No pitting was observed in either PCH 2 O-0.5M LiAsF 6 mixtures or mixed DMEH 2 O-0.5M LiAsF 6 solutions if the polarizations were conducted below the oxidation potential [1800mV ( sce )] of the hexafluoroarsenate electrolyte. It is apparent that even small amounts of water were sufficient to stabilize the passive film on stainless steel through a probable oxide-oxyhydroxide formation. Pitting of the 304 stainless steel was observed in both mixed organic-water solutions at potentials above the oxidation potential of AsF 6 − because of the lack of passivating mechanisms such as salt film formation, electropolymerization, or oxide-oxyhydroxide formation." @default.
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- W2027675974 date "1995-05-01" @default.
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- W2027675974 title "The passive behavior of 304 stainless steel in PCH2O and DMEH2O mixtures" @default.
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- W2027675974 doi "https://doi.org/10.1016/0013-4686(94)00353-3" @default.
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