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- W2027676470 abstract "Catecholate and semiquinone complexes of cobalt(II) and cobalt(III) with the macrocyclic ligand DL-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane have been synthesized and characterized. The dioxolene ligands are 3,5-di-t-butylcatechol and tetrachlorocatechol. Evidence is presented that oxidation of cobalt(II) to cobalt(III) occurs before oxidation of catecholate to semiquinone and quinone. The energies of the charge transfer bands either LMCT and MLCT are discussed in terms of electrochemical potentials." @default.
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- W2027676470 date "1989-09-01" @default.
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- W2027676470 title "Redox potentials and charge transfer spectra of catecholate and semiquinone adducts of a cobalt-tetraazamacrocyclic complex" @default.
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- W2027676470 doi "https://doi.org/10.1016/s0020-1693(00)87148-0" @default.
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