FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2027720462> ?p ?o ?g. }

• W2027720462 abstract "The conditions under which the attractive electron-electron interactions are realized in the monocations of sigma-conjugated cyanodienes such as C(6)N(4)H(4), C(8)N(6)H(4), and C(10)N(8)H(4) and of pi-conjugated acenes are discussed. The total electron-phonon coupling constants for the monocations l(HOMO) of cyanodienes are much larger than those for the monocations of acenes. The strong sigma orbital interactions between two neighboring atoms in the highest occupied molecular orbitals (HOMO) of sigma-conjugated cyanodienes are the main reason for the calculated results. Furthermore, we discuss how the conditions under which the monocation crystals become good conductor are related to the molecular size. Both the l(HOMO) values and the reorganization energies between the neutral molecules and the monocations decrease with an increase in molecular size in cyanodienes. The calculated results for the sigma-conjugated cyanodienes are compared with those for the pi-conjugated acenes in order to investigate how the CH-N substitutions in cyanodienes are closely related to the l(HOMO) values and the reorganization energies. Both the l(HOMO) and the reorganization energies in the positively charged sigma-conjugated cyanodienes are much larger than those in the positively charged pi-conjugated acenes. This means that in order to become good conductors, the positively charged sigma-conjugated cyanodienes need larger overlap integral between two adjacent molecules than the positively charged pi-conjugated acenes. On the other hand, since the l(HOMO) values for cyanodienes are much larger than those for acenes, the condition of attractive electron-electron interactions is more easily to be realized in the monocations of cyanodienes than in the monocations of acenes. It is suggested that the positively charged sigma-conjugated cyanodienes cannot easily become good conductors, but the conditions under which the electron-electron interactions become attractive are realized more easily in the positively charged sigma-conjugated cyanodienes than in the positively charged pi-conjugated acenes." @default.
• W2027720462 created "2016-06-24" @default.
• W2027720462 creator A5042734737 @default.
• W2027720462 creator A5059147537 @default.
• W2027720462 date "2005-09-01" @default.
• W2027720462 modified "2023-09-23" @default.
• W2027720462 title "Vibronic interactions and possible electron pairing in positively charged cyanodienes" @default.
• W2027720462 cites W1564532015 @default.
• W2027720462 cites W1605005332 @default.
• W2027720462 cites W1653194759 @default.
• W2027720462 cites W1969627147 @default.
• W2027720462 cites W1970868308 @default.
• W2027720462 cites W1972125661 @default.
• W2027720462 cites W1972216372 @default.
• W2027720462 cites W1976941865 @default.
• W2027720462 cites W1978762857 @default.
• W2027720462 cites W1988304487 @default.
• W2027720462 cites W1989060531 @default.
• W2027720462 cites W1992414401 @default.
• W2027720462 cites W1993119139 @default.
• W2027720462 cites W1997448295 @default.
• W2027720462 cites W1997758288 @default.
• W2027720462 cites W2000813860 @default.
• W2027720462 cites W2001829135 @default.
• W2027720462 cites W2002638064 @default.
• W2027720462 cites W2011681768 @default.
• W2027720462 cites W2012340902 @default.
• W2027720462 cites W2016664481 @default.
• W2027720462 cites W2020783003 @default.
• W2027720462 cites W2021581205 @default.
• W2027720462 cites W2023271753 @default.
• W2027720462 cites W2034032730 @default.
• W2027720462 cites W2036241770 @default.
• W2027720462 cites W2039527763 @default.
• W2027720462 cites W2044421664 @default.
• W2027720462 cites W2054220663 @default.
• W2027720462 cites W2054682233 @default.
• W2027720462 cites W2058132714 @default.
• W2027720462 cites W2058363175 @default.
• W2027720462 cites W2064277800 @default.
• W2027720462 cites W2067898870 @default.
• W2027720462 cites W2072703702 @default.
• W2027720462 cites W2074573245 @default.
• W2027720462 cites W2078526451 @default.
• W2027720462 cites W2082665299 @default.
• W2027720462 cites W2086699068 @default.
• W2027720462 cites W2086957099 @default.
• W2027720462 cites W2087625426 @default.
• W2027720462 cites W2092211141 @default.
• W2027720462 cites W2094642658 @default.
• W2027720462 cites W2098560244 @default.
• W2027720462 cites W2143981217 @default.
• W2027720462 cites W2144373174 @default.
• W2027720462 cites W2944814608 @default.
• W2027720462 cites W2952163144 @default.
• W2027720462 doi "https://doi.org/10.1063/1.1993553" @default.
• W2027720462 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16164356" @default.
• W2027720462 hasPublicationYear "2005" @default.
• W2027720462 type Work @default.
• W2027720462 sameAs 2027720462 @default.
• W2027720462 citedByCount "5" @default.
• W2027720462 crossrefType "journal-article" @default.
• W2027720462 hasAuthorship W2027720462A5042734737 @default.
• W2027720462 hasAuthorship W2027720462A5059147537 @default.
• W2027720462 hasConcept C112613896 @default.
• W2027720462 hasConcept C121332964 @default.
• W2027720462 hasConcept C139358910 @default.
• W2027720462 hasConcept C147597530 @default.
• W2027720462 hasConcept C159467904 @default.
• W2027720462 hasConcept C178790620 @default.
• W2027720462 hasConcept C184779094 @default.
• W2027720462 hasConcept C185592680 @default.
• W2027720462 hasConcept C32909587 @default.
• W2027720462 hasConcept C521977710 @default.
• W2027720462 hasConcept C8010536 @default.
• W2027720462 hasConceptScore W2027720462C112613896 @default.
• W2027720462 hasConceptScore W2027720462C121332964 @default.
• W2027720462 hasConceptScore W2027720462C139358910 @default.
• W2027720462 hasConceptScore W2027720462C147597530 @default.
• W2027720462 hasConceptScore W2027720462C159467904 @default.
• W2027720462 hasConceptScore W2027720462C178790620 @default.
• W2027720462 hasConceptScore W2027720462C184779094 @default.
• W2027720462 hasConceptScore W2027720462C185592680 @default.
• W2027720462 hasConceptScore W2027720462C32909587 @default.
• W2027720462 hasConceptScore W2027720462C521977710 @default.
• W2027720462 hasConceptScore W2027720462C8010536 @default.
• W2027720462 hasIssue "9" @default.
• W2027720462 hasLocation W20277204621 @default.
• W2027720462 hasLocation W20277204622 @default.
• W2027720462 hasOpenAccess W2027720462 @default.
• W2027720462 hasPrimaryLocation W20277204621 @default.
• W2027720462 hasRelatedWork W2007380041 @default.
• W2027720462 hasRelatedWork W2007414193 @default.
• W2027720462 hasRelatedWork W2071073691 @default.
• W2027720462 hasRelatedWork W2083597126 @default.
• W2027720462 hasRelatedWork W2105042799 @default.
• W2027720462 hasRelatedWork W2109409670 @default.
• W2027720462 hasRelatedWork W2159845392 @default.
• W2027720462 hasRelatedWork W2177849522 @default.
• W2027720462 hasRelatedWork W2376259635 @default.

• next