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- W2027740229 abstract "The surprisingly facile conversion (isomerization) of 2-formyl-arylketones into 3-substituted phthalides, as observed for the marine natural product pestalone and its per-O-methylated derivative, was investigated using a series of simple 2-acylbenzaldehydes as substrates. The transformation generally proceeds smoothly in DMSO, either in a Cannizarro–Tishchenko-type reaction under nucleophile catalysis (NaCN) or under photochemical conditions (DMSO, 350 nm)." @default.
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- W2027740229 date "2012-04-22" @default.
- W2027740229 modified "2023-10-07" @default.
- W2027740229 title "Nucleophile- or Light-Induced Synthesis of 3-Substituted Phthalides from 2-Formylarylketones" @default.
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- W2027740229 doi "https://doi.org/10.1021/ol300757m" @default.
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