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• W2027758000 abstract "The filling of carbon nanotubes, which vary in diameter and morphology, is directly observed by molecular dynamics computer simulation with a potential model which thermodynamically favors a four-coordinate bulk crystal structure. Inorganic nanotube (INT) structures form which are based on percolating hexagonal nets. For small carbon nanotube diameters the filling is shown to proceed via an internal wetting mechanism, which depends on the internal carbon nanotube area rather than the free volume. Both single- and double-walled INTs are predicted to form. The atomistic formation mechanisms are discussed and an intermediate structure identified. The INT structures, including the observed intermediate, are discussed by reference to a simple energy landscape. The formation energetics are discussed in terms of a simple analytical model which combines the INT strain energy and the tube-tube interactions. An effective phase diagram, which predicts the INT morphologies as a function of carbon nanotube diameter, is derived and discussed with respect to the analytical model." @default.
• W2027758000 created "2016-06-24" @default.
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• W2027758000 date "2006-03-28" @default.
• W2027758000 modified "2023-09-23" @default.
• W2027758000 title "The formation of low-dimensional inorganic nanotube crystallites in carbon nanotubes" @default.
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• W2027758000 doi "https://doi.org/10.1063/1.2179791" @default.
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