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- W2027771805 abstract "In this paper, we present a technique for equilibria characterization of activated carbon having slit-shaped pores. This method was first developed by Do (Do, D. D. A new method for the characterisation of micro−mesoporous materials. Presented at the International Symposium on New Trends in Colloid and Interface Science, September 24−26, 1998, Chiba, Japan) and applied by his group and other groups for characterization of pore size distribution (PSD) as well as adsorption equilibria determination of a wide range of hydrocarbons. It is refined in this paper and compared with the grand canonical Monte Carlo (GCMC) simulation and density functional theory (DFT). The refined theory results in a good agreement between the pore filling pressure versus pore width and those obtained by GCMC and DFT. Furthermore, our local isotherms are qualitatively in good agreement with those obtained by the GCMC simulations. The main advantage of this method is that it is about 4 orders of magnitude faster than the GCMC simulations, making it suitable for optimization studies and design purposes. Finally, we apply our method and the GCMC in the derivation of the PSD of a commercial activated carbon. It was found that the PSD derived from our method is comparable to that derived from the GCMC simulations." @default.
- W2027771805 created "2016-06-24" @default.
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- W2027771805 date "2003-09-01" @default.
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- W2027771805 title "Refined Method of Potential Enhancement in the Equilibria Characterization of Activated Carbon. Comparison with GCMC and DFT" @default.
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- W2027771805 doi "https://doi.org/10.1021/la020834q" @default.
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