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• W2027778082 abstract "The synthesis, characterization and study of the three ferrocenyl Schiff bases: [(η5-C5H5)Fe{(η5-C5H4)–CHN–CH2–CH2–N(CH3)2}] (1a), [(η5-C5H5)Fe{(η5-C5H4)–CHN–CH2–CH2–S–CH2–CH3}] (1b) and [(η5-C5H5)Fe{(η5-C5H4)–CHN–CH(COOCH3)–CH2–CH2–S–CH3}] (1c) are reported. Reactivity studies of these substrates versus palladium (II) and platinum (II) salts have allowed us to isolate and characterize different sorts of complex. The coordination complexes: cis-[M(ligand)Cl2] {where M=Pd (2a–2c) or Pt (3a–3c)} were prepared by treatment of the corresponding ligand and Na2[PdCl4] (for 2a–2c) or cis-[PtCl2(dmso)2] (for 3a–3c) in methanol. In compounds 2, 3a–c the ligand acts as a neutral bidentate group. The cyclopalladated complex: [Pd{(η5-C5H5)Fe[(η5-C5H3)–CHN–CH2–CH2–N(CH3)2]}Cl] (4a) can be isolated by reaction of stoichiometric amounts of 1a, Na2[PdCl4] and Na(CH3COO) · 3H2O in methanol for 8 days. In complex 4a the ligand acts as a monoanionic (C, N, N′)− terdentate group. The reaction of compound 4a with an equimolar amount of PPh3 produces [Pd{(η5-C5H5)Fe[(η5-C5H3)–CHN–CH2–CH2–N(CH3)2]}Cl(PPh3)], in which the ligand acts as a monoanionic (C, N)− bidentate ligand. All the compounds included in this study have been characterized by infrared and NMR spectroscopy and complex 2a has also been characterized structurally: monoclinic, P21/m, with a=6.034(2) Å, b=14.502(2) Å, c=10.236(2) Å and β=104.61(2)°. The crystal structure of complex 2a reveals that the imine adopts the Z-form." @default.
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• W2027778082 date "1999-04-01" @default.
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• W2027778082 title "Palladium (II) and platinum (II) compounds containing bi- and terdentate ferrocenyl ligands. X-ray crystal structure of cis-[Pd{(η5-C5H5)Fe{(η5-C5H4)–CHN–CH2–CH2–N(CH3)2]}Cl2]" @default.
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• W2027778082 doi "https://doi.org/10.1016/s0022-328x(98)01077-8" @default.
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