Matches in SemOpenAlex for { <https://semopenalex.org/work/W2027832314> ?p ?o ?g. }
- W2027832314 endingPage "147" @default.
- W2027832314 startingPage "140" @default.
- W2027832314 abstract "A tungsten phosphide, WP, hydrotreating catalyst was prepared by temperature-programmed reduction of an X-ray amorphous tungsten phosphate at a heating rate of 0.0167 K s−1 and a 2-h soak at the final temperature of 938 K. Characterization of intermediates quenched at different temperatures revealed a single crystalline reaction product whose specific CO uptake and BET surface areas passed through a maximum of 12 μmol g−1 and 15 m2 g−1, respectively, at 873 K. Heating rate variation measurements gave an apparent first-order activation energy of 148 kJ mol−1 for the reduction. Tungsten phosphide was catalytically active in the hydrodenitrogenation and hydrodesulfurization reactions of a simulated light oil consisting of 20 wt% tetralin, 76 wt% tetradecane, 2000 wppm N as quinoline, 3000 wppm S as dibenzothiophene, and 500 wppm O as benzofuran. Measurements were made in an upflow fixed-bed reactor operated at 3.1 MPa and 643 K and gave conversion levels at steady state for the WP catalyst of 58% HDN and 67% HDS. These conversions were superior to those found for WC, W2N, and WS2 tested under the same conditions." @default.
- W2027832314 created "2016-06-24" @default.
- W2027832314 creator A5000432967 @default.
- W2027832314 creator A5013413769 @default.
- W2027832314 creator A5017967519 @default.
- W2027832314 date "2001-05-01" @default.
- W2027832314 modified "2023-10-14" @default.
- W2027832314 title "Synthesis and Activity of a New Catalyst for Hydroprocessing: Tungsten Phosphide" @default.
- W2027832314 cites W135337123 @default.
- W2027832314 cites W1517866331 @default.
- W2027832314 cites W1574924608 @default.
- W2027832314 cites W1598967311 @default.
- W2027832314 cites W1965549692 @default.
- W2027832314 cites W1967906015 @default.
- W2027832314 cites W1971488678 @default.
- W2027832314 cites W1972801366 @default.
- W2027832314 cites W1972993042 @default.
- W2027832314 cites W1974145243 @default.
- W2027832314 cites W1975626999 @default.
- W2027832314 cites W1985113227 @default.
- W2027832314 cites W1986404375 @default.
- W2027832314 cites W1986523195 @default.
- W2027832314 cites W1992170971 @default.
- W2027832314 cites W2000726160 @default.
- W2027832314 cites W2004476784 @default.
- W2027832314 cites W2004778392 @default.
- W2027832314 cites W2005997551 @default.
- W2027832314 cites W2006002357 @default.
- W2027832314 cites W2009379064 @default.
- W2027832314 cites W2010893896 @default.
- W2027832314 cites W2013475435 @default.
- W2027832314 cites W2018823200 @default.
- W2027832314 cites W2022754188 @default.
- W2027832314 cites W2026156431 @default.
- W2027832314 cites W2026950260 @default.
- W2027832314 cites W2028283748 @default.
- W2027832314 cites W2033375108 @default.
- W2027832314 cites W2039843886 @default.
- W2027832314 cites W2046590572 @default.
- W2027832314 cites W2050230950 @default.
- W2027832314 cites W2052887169 @default.
- W2027832314 cites W2057685126 @default.
- W2027832314 cites W2060896608 @default.
- W2027832314 cites W2062244312 @default.
- W2027832314 cites W2068156894 @default.
- W2027832314 cites W2074375112 @default.
- W2027832314 cites W2077355560 @default.
- W2027832314 cites W2079714386 @default.
- W2027832314 cites W2079742507 @default.
- W2027832314 cites W2080953124 @default.
- W2027832314 cites W2082715955 @default.
- W2027832314 cites W2084072097 @default.
- W2027832314 cites W2084214802 @default.
- W2027832314 cites W2085208616 @default.
- W2027832314 cites W2089605766 @default.
- W2027832314 cites W2092778554 @default.
- W2027832314 cites W2095219647 @default.
- W2027832314 cites W2120497186 @default.
- W2027832314 cites W2130033504 @default.
- W2027832314 cites W2153468258 @default.
- W2027832314 cites W2165898861 @default.
- W2027832314 cites W2952421994 @default.
- W2027832314 cites W4211081178 @default.
- W2027832314 cites W4232176340 @default.
- W2027832314 doi "https://doi.org/10.1006/jcat.2001.3189" @default.
- W2027832314 hasPublicationYear "2001" @default.
- W2027832314 type Work @default.
- W2027832314 sameAs 2027832314 @default.
- W2027832314 citedByCount "130" @default.
- W2027832314 countsByYear W20278323142012 @default.
- W2027832314 countsByYear W20278323142013 @default.
- W2027832314 countsByYear W20278323142014 @default.
- W2027832314 countsByYear W20278323142015 @default.
- W2027832314 countsByYear W20278323142016 @default.
- W2027832314 countsByYear W20278323142017 @default.
- W2027832314 countsByYear W20278323142018 @default.
- W2027832314 countsByYear W20278323142019 @default.
- W2027832314 countsByYear W20278323142020 @default.
- W2027832314 countsByYear W20278323142021 @default.
- W2027832314 countsByYear W20278323142022 @default.
- W2027832314 countsByYear W20278323142023 @default.
- W2027832314 crossrefType "journal-article" @default.
- W2027832314 hasAuthorship W2027832314A5000432967 @default.
- W2027832314 hasAuthorship W2027832314A5013413769 @default.
- W2027832314 hasAuthorship W2027832314A5017967519 @default.
- W2027832314 hasConcept C13965031 @default.
- W2027832314 hasConcept C161790260 @default.
- W2027832314 hasConcept C178790620 @default.
- W2027832314 hasConcept C179104552 @default.
- W2027832314 hasConcept C185592680 @default.
- W2027832314 hasConcept C197129369 @default.
- W2027832314 hasConcept C2778216191 @default.
- W2027832314 hasConcept C2778570275 @default.
- W2027832314 hasConcept C2778949310 @default.
- W2027832314 hasConcept C2780654602 @default.
- W2027832314 hasConcept C542268612 @default.
- W2027832314 hasConceptScore W2027832314C13965031 @default.
- W2027832314 hasConceptScore W2027832314C161790260 @default.