FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2027837712> ?p ?o ?g. }

• W2027837712 endingPage "3521" @default.
• W2027837712 startingPage "3501" @default.
• W2027837712 abstract "This study presents a thermodynamic analysis of the relationship between molecular size, hydrophobicity, aqueous solubility and octanol-water partitioning for several classes of hydrophobic organic compounds including chlorinated dibenzo p-dioxins, PCBs, polynuclear aromatic hydrocarbons, alkylbenzenes, linear alcohols and alkanes. The purpose of the thermodynamic analysis is to explore the contribution of chemical-water and chemical-chemical interactions involved in the aqueous solution process. This is important for the development of relationships between the molecular structure and environmentally relevant properties of organic chemicals. The results show that the free energy of aqueous solvation is virtually independent on the molar volume of the solute for each of the congeneric series that was investigated. Within each congeneric series, congeners are therefore approximately equally “hydrophobic”, and the relationship between the aqueous solubility of (subcooled) liquid hydrophobic chemicals and molecular volume predominantly reflects the dependence of chemical-chemical interactions on the molecular volume in the (subcooled) liquid phase, rather than chemical-water interactions as is usually assumed. The results indicate that improvements of quantitative structure-aqueous solubility relationships may be achieved by modelling chemical-chemical interactions in the pure (subcooled) liquid phase, rather than merely chemical-water interaction, and that within congeneric series of non-polar organic substances, an increase in octanol-water and environmental partition coefficients with increasing congener size is due to an increase in the congener's lipophilicity, not hydrophobicity." @default.
• W2027837712 created "2016-06-24" @default.
• W2027837712 creator A5006651636 @default.
• W2027837712 creator A5059504272 @default.
• W2027837712 date "1995-09-01" @default.
• W2027837712 modified "2023-10-17" @default.
• W2027837712 title "A Thermodynamic analysis of the relationships between molecular size, hydrophobicity, aqueous solubility and octanol-water partitioning of organic chemicals" @default.
• W2027837712 cites W1967021393 @default.
• W2027837712 cites W1967080293 @default.
• W2027837712 cites W1981923961 @default.
• W2027837712 cites W1982278416 @default.
• W2027837712 cites W1985231839 @default.
• W2027837712 cites W1992210899 @default.
• W2027837712 cites W1998879475 @default.
• W2027837712 cites W2011561179 @default.
• W2027837712 cites W2017967634 @default.
• W2027837712 cites W2022516823 @default.
• W2027837712 cites W2024161968 @default.
• W2027837712 cites W2026342552 @default.
• W2027837712 cites W2032258973 @default.
• W2027837712 cites W2047977637 @default.
• W2027837712 cites W2049435064 @default.
• W2027837712 cites W2050348177 @default.
• W2027837712 cites W2052487834 @default.
• W2027837712 cites W2053798150 @default.
• W2027837712 cites W2060204471 @default.
• W2027837712 cites W2060504545 @default.
• W2027837712 cites W2063235647 @default.
• W2027837712 cites W2071267117 @default.
• W2027837712 cites W2071472423 @default.
• W2027837712 cites W2072073580 @default.
• W2027837712 cites W2073636953 @default.
• W2027837712 cites W2073775843 @default.
• W2027837712 cites W2079187203 @default.
• W2027837712 cites W2080972342 @default.
• W2027837712 cites W2090884527 @default.
• W2027837712 cites W2092181124 @default.
• W2027837712 cites W2093847319 @default.
• W2027837712 cites W2134036374 @default.
• W2027837712 cites W2289860625 @default.
• W2027837712 cites W2312702627 @default.
• W2027837712 cites W2319369292 @default.
• W2027837712 cites W2325836407 @default.
• W2027837712 cites W2334462412 @default.
• W2027837712 doi "https://doi.org/10.1016/0045-6535(95)00202-j" @default.
• W2027837712 hasPublicationYear "1995" @default.
• W2027837712 type Work @default.
• W2027837712 sameAs 2027837712 @default.
• W2027837712 citedByCount "32" @default.
• W2027837712 countsByYear W20278377122012 @default.
• W2027837712 countsByYear W20278377122013 @default.
• W2027837712 countsByYear W20278377122016 @default.
• W2027837712 countsByYear W20278377122019 @default.
• W2027837712 countsByYear W20278377122021 @default.
• W2027837712 crossrefType "journal-article" @default.
• W2027837712 hasAuthorship W2027837712A5006651636 @default.
• W2027837712 hasAuthorship W2027837712A5059504272 @default.
• W2027837712 hasConcept C148093993 @default.
• W2027837712 hasConcept C155574463 @default.
• W2027837712 hasConcept C175528265 @default.
• W2027837712 hasConcept C178790620 @default.
• W2027837712 hasConcept C184651966 @default.
• W2027837712 hasConcept C185592680 @default.
• W2027837712 hasConcept C192552737 @default.
• W2027837712 hasConcept C201399114 @default.
• W2027837712 hasConcept C2776226600 @default.
• W2027837712 hasConcept C2777691172 @default.
• W2027837712 hasConcept C2779348937 @default.
• W2027837712 hasConcept C32909587 @default.
• W2027837712 hasConceptScore W2027837712C148093993 @default.
• W2027837712 hasConceptScore W2027837712C155574463 @default.
• W2027837712 hasConceptScore W2027837712C175528265 @default.
• W2027837712 hasConceptScore W2027837712C178790620 @default.
• W2027837712 hasConceptScore W2027837712C184651966 @default.
• W2027837712 hasConceptScore W2027837712C185592680 @default.
• W2027837712 hasConceptScore W2027837712C192552737 @default.
• W2027837712 hasConceptScore W2027837712C201399114 @default.
• W2027837712 hasConceptScore W2027837712C2776226600 @default.
• W2027837712 hasConceptScore W2027837712C2777691172 @default.
• W2027837712 hasConceptScore W2027837712C2779348937 @default.
• W2027837712 hasConceptScore W2027837712C32909587 @default.
• W2027837712 hasIssue "6" @default.
• W2027837712 hasLocation W20278377121 @default.
• W2027837712 hasOpenAccess W2027837712 @default.
• W2027837712 hasPrimaryLocation W20278377121 @default.
• W2027837712 hasRelatedWork W1559185053 @default.
• W2027837712 hasRelatedWork W1995541271 @default.
• W2027837712 hasRelatedWork W2011145097 @default.
• W2027837712 hasRelatedWork W2022386059 @default.
• W2027837712 hasRelatedWork W2024149655 @default.
• W2027837712 hasRelatedWork W2030840504 @default.
• W2027837712 hasRelatedWork W2913541795 @default.
• W2027837712 hasRelatedWork W3003976389 @default.
• W2027837712 hasRelatedWork W3017205698 @default.
• W2027837712 hasRelatedWork W4379536151 @default.
• W2027837712 hasVolume "31" @default.
• W2027837712 isParatext "false" @default.
• W2027837712 isRetracted "false" @default.

• next