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- W2027838285 abstract "Thermal decomposition of imipramine hydrochloride and trimipramine maleate has been investigated isothermally and nonisothermally. The kinetic parameters, namely the activation energy Ea and the Arrhenius preexponential term A, were calculated. Applying the theory of activated complex to the process of decomposition one calculated ΔS≠, ΔH≠, and ΔG≠ for the reaction. The values of Ea as well as the thermodynamic functions did not vary significantly with temperature of the reaction whereas the preexponential term showed a significant dependence on the reaction temperature. Both imipramine hydrochloride and trimipramine maleate showed two main steps of decomposition. Each step proved to be a first-order reaction. The rate constant was calculated for each step, and the results were analyzed statistically. © 2003 Wiley Periodicals, Inc. Int J Chem Kinet 35: 166–179, 2003" @default.
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- W2027838285 date "2003-01-01" @default.
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- W2027838285 title "Kinetics and thermodynamic parameters of the thermal decomposition of imipramine hydrochloride and trimipramine maleate" @default.
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- W2027838285 doi "https://doi.org/10.1002/kin.10107" @default.
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