FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2027849992> ?p ?o ?g. }

• W2027849992 endingPage "166" @default.
• W2027849992 startingPage "155" @default.
• W2027849992 abstract "A new method for the in situ measurement of stable Si isotope ratio using UV-femtosecond laser ablation connected to a multiple-collector inductively coupled plasma mass spectrometer (MC-ICP-MS) has been established. The use of medium mass resolution mode (with a resolving power m/Δm = 8000) permits to resolve spectral interferences on 28Si, 29Si and 30Si allowing for determination of the 29Si/28Si and 30Si/28Si ratios with high accuracy and precision on wide, interference-free plateaus. A three-isotope plot demonstrated that interferences, if existing, are negligible for Si isotope ratios. The laser spot size is 35 μm and measurements are made using square rasters of 150 μm side length. Different types of elemental Si, Si-oxide and silicate matrices have been analysed by laser ablation using the international standard NBS28 as the bracketing standard. Thus δ29Si and δ30Si have been determined for the silicon isotope standard IRMM-017 (δ30Si ± 2 S.D. = − 1.26 ± 0.24‰; n = 89) and BigBatch (δ30Si = − 10.55 ± 0.42‰; n = 15), as well as San Carlos Olivine (δ30Si = − 0.81 ± 0.19‰; n = 14), Caltech Rose Quartz (δ30Si = 0.10 ± 0.13‰; n = 14) sponge needles (Stylocordyla borealis; δ30Si = − 2.19 ± 0.32‰; n = 14) and JER-diopside glass (δ30Si = 0 ± 0.09‰; n = 14) samples. The overall repeatability achievable is 0.15‰ (2 S.D.) on δ29Si and 0.24‰ (2 S.D.) on δ30Si. The silicon isotope standard IRMM-018 has also been measured and was confirmed to be heterogeneous. The two isotope ratios follow an equilibrium mass-dependent fractionation law which can be represented as δ30Si = 1.93 × δ29Si. Published extractions methods have been used to wet-chemically purify Si from the JER-diopside glass. The Si extracted was presented as Si-gel and ablated like a solid. The results show excellent agreement with in situ measurements of this glass that confirms that this technique can be employed to a wide variety of matrices, including Si purified from solution. The new technique presents a viable alternative to solution MC-ICP-MS for bulk measurements and the most precise technique so far for in situ measurement of Si isotope ratios." @default.
• W2027849992 created "2016-06-24" @default.
• W2027849992 creator A5013567795 @default.
• W2027849992 creator A5026674448 @default.
• W2027849992 creator A5079580286 @default.
• W2027849992 creator A5089274529 @default.
• W2027849992 date "2008-03-01" @default.
• W2027849992 modified "2023-10-10" @default.
• W2027849992 title "In situ determination of precise stable Si isotope ratios by UV-femtosecond laser ablation high-resolution multi-collector ICP-MS" @default.
• W2027849992 cites W1584534821 @default.
• W2027849992 cites W1830824796 @default.
• W2027849992 cites W1936265505 @default.
• W2027849992 cites W1954964785 @default.
• W2027849992 cites W1966974071 @default.
• W2027849992 cites W1971008779 @default.
• W2027849992 cites W1980784506 @default.
• W2027849992 cites W1993564178 @default.
• W2027849992 cites W1994358078 @default.
• W2027849992 cites W1998959225 @default.
• W2027849992 cites W2001268450 @default.
• W2027849992 cites W2001404719 @default.
• W2027849992 cites W2002242559 @default.
• W2027849992 cites W2003074745 @default.
• W2027849992 cites W2011006776 @default.
• W2027849992 cites W2013995291 @default.
• W2027849992 cites W2015250268 @default.
• W2027849992 cites W2022296173 @default.
• W2027849992 cites W2024260409 @default.
• W2027849992 cites W2025501304 @default.
• W2027849992 cites W2032017543 @default.
• W2027849992 cites W2041885277 @default.
• W2027849992 cites W2042123920 @default.
• W2027849992 cites W2042448116 @default.
• W2027849992 cites W2043335430 @default.
• W2027849992 cites W2054402757 @default.
• W2027849992 cites W2055131531 @default.
• W2027849992 cites W2055728552 @default.
• W2027849992 cites W2058484309 @default.
• W2027849992 cites W2063196934 @default.
• W2027849992 cites W2064723558 @default.
• W2027849992 cites W2069825726 @default.
• W2027849992 cites W2073821509 @default.
• W2027849992 cites W2075412484 @default.
• W2027849992 cites W2077455999 @default.
• W2027849992 cites W2078817169 @default.
• W2027849992 cites W2080584766 @default.
• W2027849992 cites W2081993348 @default.
• W2027849992 cites W2082701822 @default.
• W2027849992 cites W2084871787 @default.
• W2027849992 cites W2085562887 @default.
• W2027849992 cites W2085869834 @default.
• W2027849992 cites W2086427849 @default.
• W2027849992 cites W2092480611 @default.
• W2027849992 cites W2094951791 @default.
• W2027849992 cites W2125240672 @default.
• W2027849992 cites W2127888210 @default.
• W2027849992 cites W2128031863 @default.
• W2027849992 cites W2137206629 @default.
• W2027849992 cites W2160883896 @default.
• W2027849992 cites W2338601100 @default.
• W2027849992 doi "https://doi.org/10.1016/j.chemgeo.2007.12.003" @default.
• W2027849992 hasPublicationYear "2008" @default.
• W2027849992 type Work @default.
• W2027849992 sameAs 2027849992 @default.
• W2027849992 citedByCount "74" @default.
• W2027849992 countsByYear W20278499922012 @default.
• W2027849992 countsByYear W20278499922013 @default.
• W2027849992 countsByYear W20278499922014 @default.
• W2027849992 countsByYear W20278499922015 @default.
• W2027849992 countsByYear W20278499922016 @default.
• W2027849992 countsByYear W20278499922017 @default.
• W2027849992 countsByYear W20278499922018 @default.
• W2027849992 countsByYear W20278499922019 @default.
• W2027849992 countsByYear W20278499922020 @default.
• W2027849992 countsByYear W20278499922021 @default.
• W2027849992 countsByYear W20278499922022 @default.
• W2027849992 countsByYear W20278499922023 @default.
• W2027849992 crossrefType "journal-article" @default.
• W2027849992 hasAuthorship W2027849992A5013567795 @default.
• W2027849992 hasAuthorship W2027849992A5026674448 @default.
• W2027849992 hasAuthorship W2027849992A5079580286 @default.
• W2027849992 hasAuthorship W2027849992A5089274529 @default.
• W2027849992 hasConcept C113196181 @default.
• W2027849992 hasConcept C120665830 @default.
• W2027849992 hasConcept C121332964 @default.
• W2027849992 hasConcept C138268822 @default.
• W2027849992 hasConcept C154945302 @default.
• W2027849992 hasConcept C162356407 @default.
• W2027849992 hasConcept C164304813 @default.
• W2027849992 hasConcept C178790620 @default.
• W2027849992 hasConcept C185544564 @default.
• W2027849992 hasConcept C185592680 @default.
• W2027849992 hasConcept C191897082 @default.
• W2027849992 hasConcept C192562407 @default.
• W2027849992 hasConcept C2777335606 @default.
• W2027849992 hasConcept C2779188808 @default.
• W2027849992 hasConcept C41008148 @default.
• W2027849992 hasConcept C43617362 @default.

• next