Matches in SemOpenAlex for { <https://semopenalex.org/work/W2027866197> ?p ?o ?g. }
Showing items 1 to 85 of
85
with 100 items per page.
- W2027866197 endingPage "6077" @default.
- W2027866197 startingPage "6069" @default.
- W2027866197 abstract "A method is presented for the preparation of silica-based alkylsilane stationary phases using octanol as a displaceable surface template to control the rate of alkylsilane condensation with the silica surface, and thereby, the resulting alkylsilane surface coverage. This method improves upon conventional preparation schemes by allowing alkylsilane stationary phases of systematically varying surface coverage to be prepared from a single reaction mixture and a single precursor molecule without rigorous control of water content of the solution or of the silica. Octadecylsilane stationary phases ranging in surface coverage from approximately 3.5 to 6.0 micromol/m(2) were synthesized using one set of experimental conditions with variation of only the octadecylsilane/octanol ratio. The conformational order of the octadecylsilane alkyl chains was assessed using Raman spectroscopy and was found to increase with increasing surface coverage in a manner similar to stationary phases prepared by conventional routes. As chromatographic stationary phases in microbore columns for the reversed-phase separation of monosubstituted aromatic compounds, the performance of these materials is comparable to or better than that of commercially available octadecylsilane stationary phases under identical chromatographic conditions. Furthermore, the high-density stationary phases (>3.5 micromol/m(2)) prepared by this route exhibit geometric shape selectivity comparable to or better than that reported earlier for high-density octadecylsilane stationary phases prepared using conventional methods." @default.
- W2027866197 created "2016-06-24" @default.
- W2027866197 creator A5015111176 @default.
- W2027866197 creator A5078270942 @default.
- W2027866197 date "2005-08-20" @default.
- W2027866197 modified "2023-09-24" @default.
- W2027866197 title "Alkylsilane-Based Stationary Phases via a Displaceable Surface Template Approach: Synthesis, Characterization, and Chromatographic Performance" @default.
- W2027866197 cites W15877456 @default.
- W2027866197 cites W1971866869 @default.
- W2027866197 cites W1977052721 @default.
- W2027866197 cites W1981478526 @default.
- W2027866197 cites W1982423926 @default.
- W2027866197 cites W1985201781 @default.
- W2027866197 cites W1988192787 @default.
- W2027866197 cites W1990301493 @default.
- W2027866197 cites W1991296357 @default.
- W2027866197 cites W1993917151 @default.
- W2027866197 cites W1994412504 @default.
- W2027866197 cites W2005255525 @default.
- W2027866197 cites W2007121700 @default.
- W2027866197 cites W2024559610 @default.
- W2027866197 cites W2036648100 @default.
- W2027866197 cites W2041149142 @default.
- W2027866197 cites W2046083542 @default.
- W2027866197 cites W2046508757 @default.
- W2027866197 cites W2051397045 @default.
- W2027866197 cites W2053899235 @default.
- W2027866197 cites W2060548005 @default.
- W2027866197 cites W2060932925 @default.
- W2027866197 cites W2062548067 @default.
- W2027866197 cites W2072747286 @default.
- W2027866197 cites W2076659673 @default.
- W2027866197 cites W2088260706 @default.
- W2027866197 cites W2090598458 @default.
- W2027866197 cites W2164940507 @default.
- W2027866197 cites W2331407714 @default.
- W2027866197 doi "https://doi.org/10.1021/ac0511795" @default.
- W2027866197 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16159143" @default.
- W2027866197 hasPublicationYear "2005" @default.
- W2027866197 type Work @default.
- W2027866197 sameAs 2027866197 @default.
- W2027866197 citedByCount "6" @default.
- W2027866197 countsByYear W20278661972012 @default.
- W2027866197 countsByYear W20278661972016 @default.
- W2027866197 crossrefType "journal-article" @default.
- W2027866197 hasAuthorship W2027866197A5015111176 @default.
- W2027866197 hasAuthorship W2027866197A5078270942 @default.
- W2027866197 hasConcept C113196181 @default.
- W2027866197 hasConcept C118792377 @default.
- W2027866197 hasConcept C161790260 @default.
- W2027866197 hasConcept C178790620 @default.
- W2027866197 hasConcept C185592680 @default.
- W2027866197 hasConcept C2780263894 @default.
- W2027866197 hasConcept C2983406500 @default.
- W2027866197 hasConcept C43617362 @default.
- W2027866197 hasConceptScore W2027866197C113196181 @default.
- W2027866197 hasConceptScore W2027866197C118792377 @default.
- W2027866197 hasConceptScore W2027866197C161790260 @default.
- W2027866197 hasConceptScore W2027866197C178790620 @default.
- W2027866197 hasConceptScore W2027866197C185592680 @default.
- W2027866197 hasConceptScore W2027866197C2780263894 @default.
- W2027866197 hasConceptScore W2027866197C2983406500 @default.
- W2027866197 hasConceptScore W2027866197C43617362 @default.
- W2027866197 hasIssue "18" @default.
- W2027866197 hasLocation W20278661971 @default.
- W2027866197 hasLocation W20278661972 @default.
- W2027866197 hasOpenAccess W2027866197 @default.
- W2027866197 hasPrimaryLocation W20278661971 @default.
- W2027866197 hasRelatedWork W2023434535 @default.
- W2027866197 hasRelatedWork W2033357276 @default.
- W2027866197 hasRelatedWork W2082989531 @default.
- W2027866197 hasRelatedWork W2086124779 @default.
- W2027866197 hasRelatedWork W2087761197 @default.
- W2027866197 hasRelatedWork W2089818263 @default.
- W2027866197 hasRelatedWork W2402972497 @default.
- W2027866197 hasRelatedWork W2949226516 @default.
- W2027866197 hasRelatedWork W2949404879 @default.
- W2027866197 hasRelatedWork W2952979462 @default.
- W2027866197 hasVolume "77" @default.
- W2027866197 isParatext "false" @default.
- W2027866197 isRetracted "false" @default.
- W2027866197 magId "2027866197" @default.
- W2027866197 workType "article" @default.