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• W2027879560 abstract "Flow induced mechanical properties are often coupled with instabilities, spurt effects, or induced phase transitions. Recent studies have revealed that side-chain liquid crystal polymers exhibit typically shear-induced phases inside the isotropic (nonmesomorphic) liquid state. We present an experimental approach which brings a new understanding for nonlinear flow behaviors. The strategy consists in comparing the critical times issued from the flow behavior of a liquid-crystal polymer to the equilibrium orientational-order relaxation time was characterized. We demonstrate that shear-induced phases do not originate from a flow coupling to conventional orientational order parameter fluctuations. It does not also correspond to a direct coupling with the viscoelastic terminal time, leading to the conclusion that an additional relaxation process takes place with time scales longer than the terminal time. The identification of a low-frequency elastic plateau by viscoelastic measurements corroborates this conclusion." @default.
• W2027879560 created "2016-06-24" @default.
• W2027879560 creator A5008173615 @default.
• W2027879560 date "2005-11-01" @default.
• W2027879560 modified "2023-09-25" @default.
• W2027879560 title "Origin of shear-induced phase transitions in melts of liquid-crystal polymers" @default.
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• W2027879560 doi "https://doi.org/10.1103/physreve.72.051701" @default.
• W2027879560 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16383614" @default.
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