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- W2027910078 abstract "Two series of platinum-germanium over alumina catalysts were prepared. Both series were calcined at 673 K after the addition of both components, while series B was calcined prior to the addition of platinum at 873 K. Temperature-programmed reduction and hydrogen consumption under reactions conditions showed complete reduction of Pt(IV) to Pt(0) for all catalysts and partial reduction of the germanium(IV) precursor in the case of the high loading germanium catalysts of Series A. Series B showed no signs of germanium reduction. Benzene hydrogenation and n-butane hydrogenolysis were used as test reactions. For both series the specific activity decreased when the amount of germanium was increased. The selectivity ratios in the hydrogenolysis reaction remained constant for Series B while there was a variation in Series A with the percentage germanium on the catalyst. The results are discussed in terms of the current literature." @default.
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- W2027910078 date "1986-07-01" @default.
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- W2027910078 title "A study of the platinum-germanium catalytic system" @default.
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