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• W2027956670 endingPage "1929" @default.
• W2027956670 startingPage "1923" @default.
• W2027956670 abstract "The dinuclear complex Cp*2Os2Br4 (Cp* = pentamethylcyclopentadienyl) and related mono(pentamethylcyclopentadienyl)osmium compounds are catalysts for the ring-opening metathesis polymerization (ROMP) of norbornene. The most active catalyst prepared to date is made by treatment of Cp*2Os2Br4 with methylaluminoxane. This catalyst polymerizes norbornene with yields up to 167 kg of polymer per mol of catalyst at room temperature. The 13C NMR spectra show that the polymer is slightly blocky and that cis double bonds predominate. The polymer is insoluble in organic solvents but is swelled by many of them." @default.
• W2027956670 created "2016-06-24" @default.
• W2027956670 creator A5071024897 @default.
• W2027956670 creator A5074634487 @default.
• W2027956670 date "1999-04-08" @default.
• W2027956670 modified "2023-09-27" @default.
• W2027956670 title "Ring-Opening Metathesis Polymerization of Norbornene by Cp*₂Os₂Br₄ and Related Compounds" @default.
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• W2027956670 doi "https://doi.org/10.1021/om980434r" @default.
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