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• W2027973732 abstract "The formation of 3.5% T, 3.3% C cross-linked polyacrylamide is monitored in 75-microns-i.d. electrophoresis capillaries by Raman microprobe spectroscopy. The disappearance of the acrylamide 1292-cm-1 band is followed with 60-s time resolution for 30 min, and 2-4 min resolution for up to 10 h. Polymerization is 98% complete in 1.5 h and greater than 99% complete after 2 h. In the 900-1700-cm-1 region no bands attributable to cross-linking are observable. Reaction in the capillary follows second-order kinetics. The reaction is faster in the bulk system because heat dissipation is not sufficient to maintain a constant temperature." @default.
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• W2027973732 date "1992-10-15" @default.
• W2027973732 modified "2023-09-26" @default.
• W2027973732 title "Acrylamide polymerization kinetics in gel electrophoresis capillaries. A Raman microprobe study" @default.
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• W2027973732 doi "https://doi.org/10.1021/ac00044a023" @default.
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