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• W2027982765 abstract "Four sets of Li 2 O–ZnO–Al 2 O 3 –SiO 2 (LZAS) glass–ceramics containing different content of fluorine were fabricated. With CaF 2 content increasing, the glass transition temperature ( T g ) and crystallization temperature ( T c1 , or T c2 ) decreased as differential scanning calorimetry results showed; this phenomenon could be explained based on the Fourier‐transformed infrared spectra analysis. X‐ray diffraction ( XRD ) results indicated that CaF 2 did influence the crystallization temperatures of some crystal phase in the LZAS glass–ceramics, the transformations from glass to β‐quartz ss solid solution and β‐quartz ss to β‐spodumene occurred at lower temperatures, and the decrease could reach to 80°C. According to the scanning electron microscope analysis, the addition of F − ions can contribute to a microstructure with higher crystallinity and finer grain size. The density and average thermal coefficients of the studied glass–ceramics were influenced by the content of F − ions. All the results showed that CaF 2 did promote initial crystallization of LZAS glass and can be used as an effective nucleating agent in the LZAS system." @default.
• W2027982765 created "2016-06-24" @default.
• W2027982765 creator A5030719289 @default.
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• W2027982765 date "2014-12-22" @default.
• W2027982765 modified "2023-10-18" @default.
• W2027982765 title "Effect of CaF₂Addition on the Crystallization and Phase Formation in Li₂O-ZnO-Al₂O₃-SiO₂Glass-Ceramic" @default.
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• W2027982765 doi "https://doi.org/10.1111/ijac.12365" @default.
• W2027982765 hasPublicationYear "2014" @default.
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