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- W2028006059 abstract "Abstract This report presents the latest knowledge on surface properties by which the mechanism and intensity of the adhesion of organic coatings can be influenced on iron materials. By this, it is to be made clear above all that these surface properties depend on a large number of single factors. Since, however, their complex combined action has not been quite clear, it is not yet possible to reconcile the partly different conceptions of the most favourable condition of steel surfaces for a subsequent coating [1 -14]. On the basis of experimental results there are given reasons for the conclusion that greater attention than has been the case so far should be paid to the hydroxyl group-containing primary oxides being formed spontaneously on steel surfaces following the mechanical or chemical pretreatment during contact with air, when coating materials and techniques are selected. If such a continuous, homogeneous primary oxide layer exists, its amphoteric surface hydroxyl groups can be utilized for the chemical adhesion of suitable organic film-formers. On steels whose surface is heterogeneous due to the island-shaped distribution of primary oxides, non-metallic deposits and pollutants, homogenization can be achieved by producing a conversion layer. Usually, phosphate and oxide layers have amphoteric surface hydroxyl groups, too, whose isoelectric point (IEPS) varies with the composition, so that it is possible to select thermodynamically favourable conditions for the chemical adhesion of organic coatings." @default.
- W2028006059 created "2016-06-24" @default.
- W2028006059 creator A5004956707 @default.
- W2028006059 date "1987-06-01" @default.
- W2028006059 modified "2023-10-14" @default.
- W2028006059 title "Surface characterization of iron and steel prior to coating" @default.
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- W2028006059 doi "https://doi.org/10.1016/0033-0655(87)80003-1" @default.
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