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- W2028007789 abstract "Abstract Two sets of meso -tetraphenylzincporphyrins have been synthesized via Sonogashira coupling and Knoevenagel condensation. The photophysical and electrochemical measurements have been performed for each dye, and the photovoltaic properties of all porphyrin-based dye-sensitized solar cells (DSSCs) have been evaluated. For different linkers on β position, meso-substituents show different affections for DSSCs' performances. The matching degree of the length of linker and the size of meso -substituent could be a key point in porphyrin structure that affect the cell performance of DSSC based on porphyrin sensitizers. The highest cell performance was achieved with IId as a sensitizer and ethanol as an immersing solvent: a short-circuit photocurrent density of 9.75 mA cm −2 , an open-circuit voltage of 0.71 V, a fill factor of 0.73, and a light to electricity conversion efficiency of 5.08% under the AM 1.5 sunlight." @default.
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- W2028007789 date "2014-01-01" @default.
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- W2028007789 title "A key point of porphyrin structure affect DSSCs performance based on porphyrin sensitizers" @default.
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