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• W2028010506 endingPage "13395" @default.
• W2028010506 startingPage "13395" @default.
• W2028010506 abstract "We have studied the factors that affect the formation of different metallosupramolecular architectures by metal direct self-assembly. A synthetic route has been developed to obtain mesocates or dihelicates selectively. For this purpose a series of five bisthiosemicarbazone ligands derived from 1,3-diacetylbenzene were designed and synthesised. Namely H2LMe, H2LEt, H2LPh, H2LPhN and H2LPhOMe with different substituents on the 4-N terminal position of the thiosemicarbazone strands. The Co(II), Zn(II) and Cd(II) complexes of these ligands were prepared by an electrochemical procedure. Crystallographic studies revealed the formation of mesocates for Co(II) and Zn(II) metal ions whereas the Cd(II) complexes gave a bishelical supramolecular structure. Therefore these bisthiosemicarbazone ligands enable the selective isolation of mesocate or dihelicate complexes by using a specific metal ion." @default.
• W2028010506 created "2016-06-24" @default.
• W2028010506 creator A5014974858 @default.
• W2028010506 creator A5042153751 @default.
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• W2028010506 creator A5047319724 @default.
• W2028010506 creator A5053302880 @default.
• W2028010506 creator A5082508969 @default.
• W2028010506 date "2012-01-01" @default.
• W2028010506 modified "2023-10-09" @default.
• W2028010506 title "Metal self-recognition: a pathway to control the formation of dihelicates and mesocates" @default.
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