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- W2028013580 abstract "Abstract A new dense form of iron vanadate Fe 3+ V 5+ O 4 has been synthesized under high pressure high temperature conditions in a sealed platinum capsule. This phase cristallizes in a structure of monoclinic wolframite NiWO 4 type. The dense form of αPbO 2 type previously described by Young and Schwartz was shown to be probably a reduced form of composition Fe 1− x V 1+ x O 4 containing some tetravalent vanadium. This disordered phase was also obtained when runs were performed in unsealed capsules. The monoclinic form undergoes at 570°C an irreversible transformation to the form stable at normal pressure conditions, while the disordered form of αPbO 2 type transforms at about 540°C into intermediate form of Cr 3+ V 5+ O 4 type. The range of stability of this phase is very narrow and at about 570°C it transforms to the normal triclinic form." @default.
- W2028013580 created "2016-06-24" @default.
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- W2028013580 date "1974-12-01" @default.
- W2028013580 modified "2023-09-23" @default.
- W2028013580 title "Synthése sons Haute Pressiori d'Oxygène d'une Forme Dense Ordonée FeVO4 et Mise en Evidence dune Variété Allotropique de Structure CrVO4" @default.
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- W2028013580 doi "https://doi.org/10.1016/s0022-4596(74)80065-4" @default.
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