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• W2028049061 abstract "Solid solutions of TiB2–ZrB2 and TiB2–HfB2 were obtained under an inert atmosphere by high-energy ball-milling mixtures of Ti/Zr/B and Ti/Hf/B, respectively. Milling promoted mechanically induced self-sustaining reactions (MSR), and the ignition time was dependent on the initial composition of the mixture. The stoichiometry of Ti1−xZrxB2 and Ti1−xHfxB2 solid solutions was controlled by adjusting the atomic ratio of the reactants. The solid solutions were characterised by X-ray diffraction, transmission electron microscopy, electron diffraction, and energy dispersive X-ray spectroscopy. The results revealed that TiB2–ZrB2 possessed a nanometric microstructure and good chemical homogeneity. However, in the TiB2–HfB2 system, an inhomogeneous solid solution was obtained when a Ti-rich mixture was employed. The solid solutions showed good thermal stability; thus, can be used as raw materials for the development of technological materials for structural applications." @default.
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• W2028049061 date "2011-08-01" @default.
• W2028049061 modified "2023-10-18" @default.
• W2028049061 title "Mechanochemical synthesis of Ti1−xZrxB2 and Ti1−xHfxB2 solid solutions" @default.
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• W2028049061 doi "https://doi.org/10.1016/j.ceramint.2011.02.004" @default.
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