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- W2028061889 abstract "A pulsed HCl chemical laser is used to excite HCl molecules vibrationally in the presence of Br atoms in a discharge-flow reactor. The rate of the reaction $mathrm{Br}+mathrm{HCl}(v)ensuremath{rightarrow}mathrm{HBR}+mathrm{Cl}$ increases by a factor of ${10}^{11}$ at room temperature if $mathrm{HCl}(v=0)$ is excited into $v=2$. Excitation occurs predominantly for ${mathrm{H}}^{35}$Cl. Cl atoms generated by the laser-stimulated reaction react with ${mathrm{Br}}_{2}$ to form BrCl, which is detected by time-resolved mass spectrometry and shows an enrichment of $^{35}mathrm{Cl}$ (90% $^{35}mathrm{Cl}$)." @default.
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- W2028061889 date "1975-06-30" @default.
- W2028061889 modified "2023-10-17" @default.
- W2028061889 title "Chemical-Laser-Induced Isotopically Selective Reaction of HCl" @default.
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- W2028061889 doi "https://doi.org/10.1103/physrevlett.34.1597" @default.
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