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• W2028075030 endingPage "2164" @default.
• W2028075030 startingPage "2160" @default.
• W2028075030 abstract "In this work, poly ethylene glycol (pEG) was used as a cosolvent to control the morphology of transition metal substituted aluminophosphate molecular sieve AlPO4-5 (AFI) crystals in the solvothermal reaction system of Al(OPri)3-H3PO4-TEA-Me-H2O-pEG (Me = Cr, Ti, Fe, V). In the presence of pEG molecules, the growth rate of the Me-AFI crystals along c-direction was significantly inhibited. With the increase of the volume ratio of pEG/H2O, the aspect ratio of hexagonal prismlike Cr-AFI crystals was gradually decreased and the tabletlike crystals were obtained. Further increasing the volume ratio of pEG/H2O resulted in the novel flowerlike morphology for Cr3+- and Fe3+-substituted AFI crystals and kiwi-fruit-like morphology for Ti4+ and V5+ substituted AFI crystals. Our studies revealed that the existence of pEG molecules and the isomorphic substitution of Al or P are important for the formation of these specific morphologies." @default.
• W2028075030 created "2016-06-24" @default.
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• W2028075030 date "2008-03-01" @default.
• W2028075030 modified "2023-10-17" @default.
• W2028075030 title "Morphology Changes of Transition-Metal-Substituted Aluminophosphate Molecular Sieve AlPO₄-5 Crystals" @default.
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• W2028075030 doi "https://doi.org/10.1021/cm703317c" @default.
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