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- W2028090410 abstract "Abstract New P∩P‐ and P∩N‐ligands have been synthesised whose core structure is an [(η 6 ‐arene)Cr(CO) 3 ] unit. These new ligands, which extend the range of “Daniphos” ligands, are endowed with central and planar chirality and have been prepared through a stereoselective synthetic strategy from optically pure benzylamines bearing a second substituent on the arene other than the benzyldimethylamino group. Because the two faces of unsymmetrically 1,2‐ and 1,3‐disubstituted benzylamine are diastereotopic, which means that diastereomeric complexes arise upon coordination of theCr(CO) 3 fragment to either of these two faces, the synthetic plan has been adjusted by exploiting the trimethylsilyl group as a temporary steric modulator in order to access both complexes with high diastereoselectivity. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)" @default.
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- W2028090410 date "2007-10-23" @default.
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- W2028090410 title "Expanding the Range of “Daniphos”‐Type P∩P‐ and P∩N‐Ligands: Synthesis and Structural Characterisation of New [(η <sup>6</sup> ‐arene)Cr(CO) <sub>3</sub> ] Complexes" @default.
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- W2028090410 doi "https://doi.org/10.1002/ejic.200700568" @default.
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