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• W2028110615 abstract "On irradiation of C5Me5Re(CO)3 in the presence of C8H8, complexes C5Me5Re(CO)2(η2-C8H8) (1) as well as C5Me5Re(η6-C8H8) (2) are formed. The latter was characterised by a crystal structure analysis. The reaction of K2[C8H8] with [ReBr(CO)3(THF)2] yields a dimetallic complex (CO)3Re(μ-C8H8)Re(CO)3 (3), which has a syn-bridging structure and is fluxional in solution. The manganese complex (η5-C8H9)Mn(CO)3 can be deprotonated to give the anion [η4-C8H8)Mn(CO)3]−, which is used as a building block for heterodimetallic complexes. It reacts with cationic 12-electron fragments [LnM]+ to give dimetallic compounds [(CO)3Mn(μ-C8H8)MLn]. These complexes have either syn- or anti-bridging structures. Both structural types exhibit dynamic behaviour in solution. The carbonyl groups of complex (CO)3Mn(μ-C8H8)Rh(CO)2 were labelled with 13CO and shown to undergo very slow intermetallic scrambling." @default.
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• W2028110615 date "1999-06-01" @default.
• W2028110615 modified "2023-10-10" @default.
• W2028110615 title "The reactivity of complexed carbocycles XII: mono- and dimetallic cyclooctatetraene complexes of manganese and rhenium: synthesis, structure and dynamic behaviour" @default.
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• W2028110615 doi "https://doi.org/10.1016/s0022-328x(99)00108-4" @default.
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