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- W2028113383 abstract "The anisotropy of the dynamic properties of interlayer water molecules along the a and b axes of vanadium pentoxide hydrate, orthorhombic V2O5.nH2O, was studied using quasielastic neutron scattering (QENS) in relation to the anisotropy of the ac conductivity. The QENS spectra were analyzed using a stretched exponential function and a Lorentzian function. Both methods showed that the double-layer water molecules along the b axis are more mobile than those along the a axis. The difference in mobility between the two axes is more pronounced using a Lorentzian function analysis. These facts suggest that the diffusion coefficient of water molecules along the b axis is larger than that along the a axis, which is closely related to the ac conductivity originating from proton hopping. The anisotropy of the dynamic motion of water molecules can be attributed to the shorter b-axis length (b=3.60 A), with respect to the longer and less regular repetition of the atomic arrangements along the a axis (42.34 A)." @default.
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- W2028113383 date "2007-08-13" @default.
- W2028113383 modified "2023-10-18" @default.
- W2028113383 title "Interlayer water molecules in vanadium pentoxide hydrate. IX. Anisotropic translational diffusion leading to anisotropic ac conductivity" @default.
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- W2028113383 doi "https://doi.org/10.1063/1.2756041" @default.
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