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- W2028132949 endingPage "284114" @default.
- W2028132949 startingPage "284114" @default.
- W2028132949 abstract "The effects of network topology on the static structural, mechanical and dynamic properties of MX(2) network-forming liquids (with tetrahedral short-range order) are discussed. The network topology is controlled via a single model parameter (the anion polarizability) which effectively constrains the inter-tetrahedral linkages in a physically transparent manner. Critically, it is found to control the balance between the stability of corner- and edge-sharing tetrahedra. A potential rigidity transformation is investigated. The vibrational density of states is investigated, using an instantaneous normal model analysis, as a function of both anion polarizability and temperature. A low frequency peak is seen to appear and is shown to be correlated with the fraction of cations which are linked through solely edge-sharing structural motifs. A modified effective mean atom coordination number is proposed which allows the appearance of the low frequency feature to be understood in terms of a mean field rigidity percolation threshold." @default.
- W2028132949 created "2016-06-24" @default.
- W2028132949 creator A5005917049 @default.
- W2028132949 date "2012-06-27" @default.
- W2028132949 modified "2023-09-23" @default.
- W2028132949 title "The effects of topology on the structural, dynamic and mechanical properties of network-forming materials" @default.
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- W2028132949 doi "https://doi.org/10.1088/0953-8984/24/28/284114" @default.
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- W2028132949 hasPublicationYear "2012" @default.
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