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- W2028160275 abstract "The formation of cobalt(II) complexes with inorganic ligands in ion-exchanger solid phases has been investigated by direct spectrophotometric measurements. It was found that the stability constants of the one-to-one cobalt(II)-thiocyanate complex in the cation-exchanger phase are in all cases intrinsically higher than those in the solutions of the corresponding condition. This result can be ascribed to a low dielectric constant and high internal pressure as characteristic properties of the ion-exchanger phase, in comparison with the solution phase. This fact must be taken into consideration in using a conventional cation-exchange method for the determination of stability constants, in which the complex formation with anionic ligands in cation-exchangers has often been neglected for simplification in analysis." @default.
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- W2028160275 date "1989-01-01" @default.
- W2028160275 modified "2023-09-23" @default.
- W2028160275 title "Comparison of complexibility on inorganic cobalt(II) complexes between ion-exchanger and aqueous solution media" @default.
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