FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2028161493> ?p ?o ?g. }

• W2028161493 endingPage "801" @default.
• W2028161493 startingPage "793" @default.
• W2028161493 abstract "Abstract Small bimetallo biomimetic zinc‐based compounds containing a bridging μ‐OH functionality can be easily hydrated to yield complexes containing an intramolecular Zn–H 3 O 2 –Zn bridge. Because such bridges are intrinsically more nucleophilic than the corresponding μ‐OH functionality, this effectively activates the complex. The Zn–H 3 O 2 –Zn unit is labile, and one can successively substitute the “water” and the “hydroxide” in the bridge for methanol and methoxide to form metal‐bound HO–H–OMe and MeO–H–OMe functionalities. We have performed an extensive density functional investigation of this substitution mechanism for a series of bimetallo zinc complexes which have been synthesised and investigated by F. Meyer et al. There are two mechanisms for water/methanol exchange – an addition–elimination and a direct exchange mechanism. If the metal ions are coordinatively unsaturated, and their ligand sphere does not sterically hinder the approach of the methanol, both pathways compete with each other. For coordinatively saturated bimetallo complexes with larger ligand spheres, only the direct exchange mechanism is possible. Regardless of the mechanism operating, the exchange is facile and is controlled by the relative thermodynamic stability of the intermediates. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)" @default.
• W2028161493 created "2016-06-24" @default.
• W2028161493 creator A5026957310 @default.
• W2028161493 creator A5056414207 @default.
• W2028161493 date "2006-02-01" @default.
• W2028161493 modified "2023-09-24" @default.
• W2028161493 title "Mechanism of the MeOH/H ₂ O Substitution in a Series of Biomimetic Bimetallo Zinc‐Based H ₃ O ₂ Complexes" @default.
• W2028161493 cites W1513985552 @default.
• W2028161493 cites W1923343791 @default.
• W2028161493 cites W1950229574 @default.
• W2028161493 cites W1963923710 @default.
• W2028161493 cites W1966182479 @default.
• W2028161493 cites W1974980790 @default.
• W2028161493 cites W1977334206 @default.
• W2028161493 cites W1978756330 @default.
• W2028161493 cites W1978897227 @default.
• W2028161493 cites W1986894327 @default.
• W2028161493 cites W1987063649 @default.
• W2028161493 cites W1987727701 @default.
• W2028161493 cites W1990870114 @default.
• W2028161493 cites W1993077801 @default.
• W2028161493 cites W1993383767 @default.
• W2028161493 cites W1994103683 @default.
• W2028161493 cites W1998179744 @default.
• W2028161493 cites W1999367468 @default.
• W2028161493 cites W2002025869 @default.
• W2028161493 cites W2004565551 @default.
• W2028161493 cites W2008658661 @default.
• W2028161493 cites W2009209190 @default.
• W2028161493 cites W2010498235 @default.
• W2028161493 cites W2018210594 @default.
• W2028161493 cites W2021429546 @default.
• W2028161493 cites W2023204992 @default.
• W2028161493 cites W2023271753 @default.
• W2028161493 cites W2024461754 @default.
• W2028161493 cites W2027081645 @default.
• W2028161493 cites W2029041099 @default.
• W2028161493 cites W2030017897 @default.
• W2028161493 cites W2038767330 @default.
• W2028161493 cites W2041114202 @default.
• W2028161493 cites W2041177203 @default.
• W2028161493 cites W2042985555 @default.
• W2028161493 cites W2043039490 @default.
• W2028161493 cites W2044490585 @default.
• W2028161493 cites W2048715654 @default.
• W2028161493 cites W2052359734 @default.
• W2028161493 cites W2052654668 @default.
• W2028161493 cites W2058157350 @default.
• W2028161493 cites W2058615484 @default.
• W2028161493 cites W2068617439 @default.
• W2028161493 cites W2071749195 @default.
• W2028161493 cites W2071792596 @default.
• W2028161493 cites W2072291691 @default.
• W2028161493 cites W2075684479 @default.
• W2028161493 cites W2075858292 @default.
• W2028161493 cites W2077609268 @default.
• W2028161493 cites W2080889040 @default.
• W2028161493 cites W2083676460 @default.
• W2028161493 cites W2085966856 @default.
• W2028161493 cites W2091241048 @default.
• W2028161493 cites W2094062398 @default.
• W2028161493 cites W2104484273 @default.
• W2028161493 cites W2111031224 @default.
• W2028161493 cites W2143981217 @default.
• W2028161493 cites W2154264198 @default.
• W2028161493 cites W2165288182 @default.
• W2028161493 cites W2167701793 @default.
• W2028161493 cites W2167821124 @default.
• W2028161493 cites W2949725644 @default.
• W2028161493 cites W2950134971 @default.
• W2028161493 cites W2950590019 @default.
• W2028161493 cites W2950930190 @default.
• W2028161493 cites W3005140128 @default.
• W2028161493 cites W3005503508 @default.
• W2028161493 cites W3105938624 @default.
• W2028161493 cites W4211062846 @default.
• W2028161493 doi "https://doi.org/10.1002/ejic.200500450" @default.
• W2028161493 hasPublicationYear "2006" @default.
• W2028161493 type Work @default.
• W2028161493 sameAs 2028161493 @default.
• W2028161493 citedByCount "8" @default.
• W2028161493 countsByYear W20281614932012 @default.
• W2028161493 countsByYear W20281614932014 @default.
• W2028161493 countsByYear W20281614932015 @default.
• W2028161493 crossrefType "journal-article" @default.
• W2028161493 hasAuthorship W2028161493A5026957310 @default.
• W2028161493 hasAuthorship W2028161493A5056414207 @default.
• W2028161493 hasConcept C111185830 @default.
• W2028161493 hasConcept C116569031 @default.
• W2028161493 hasConcept C155647269 @default.
• W2028161493 hasConcept C161790260 @default.
• W2028161493 hasConcept C170493617 @default.
• W2028161493 hasConcept C178790620 @default.
• W2028161493 hasConcept C178907741 @default.
• W2028161493 hasConcept C179104552 @default.
• W2028161493 hasConcept C185592680 @default.
• W2028161493 hasConcept C201194858 @default.
• W2028161493 hasConcept C2775896084 @default.

• next