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• W2028184461 abstract "Control of coordination modes of a ligand in metal complexes is significant because the coordination modes influence catalytic properties of transition metal catalysts. Reactions of 2-diphenylphosphinoazobenzenes, which are in equilibrium with the inner phosphonium salts, with ZnCl2, W(CO)5(THF), and PtCl2(cod) gave three different coordination types of metal complexes with distinctive UV-vis absorptions. All the complexes were characterized by X-ray crystallographic analyses. In the zinc and tungsten complexes, the source molecule functions as an amide ligand and a phosphine ligand, respectively. In the platinum complex, the phosphorus molecule works as a tridentate ligand with formation of a carbon–platinum bond." @default.
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• W2028184461 date "2012-01-01" @default.
• W2028184461 modified "2023-10-17" @default.
• W2028184461 title "Different coordination modes of 2-(diphenylphosphino)azobenzenes in complexation with hard and soft metals" @default.
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• W2028184461 doi "https://doi.org/10.1039/c2dt31494k" @default.
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