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- W2028235912 abstract "Two Co(II) coordination polymers: [Co(oda)(H2O)2·H2O]n (1) and [Co(oda)(H2O)·H2O]n (2) (H2oda=oxydiacetic acid) have been synthesized under mild and hydro(solvo)thermal reaction conditions, respectively, which were characterized by single crystal X-ray determination, IR and thermogravimetric analysis. [Co(oda)(H2O)2·H2O]n has a covalently linked 1D chain structure, while [Co(oda)(H2O)·H2O]n has a covalently linked 3D chiral network with channels. They show an unusual example of topological isomerism. The structural interconversion between [Co(oda)(H2O)2·H2O]n and [Co(oda)(H2O)·H2O]n revealed that self-assembly in the synthesis and interconversion of crystalline solids is a thermodynamically controlled process." @default.
- W2028235912 created "2016-06-24" @default.
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- W2028235912 date "2003-09-01" @default.
- W2028235912 modified "2023-09-24" @default.
- W2028235912 title "Synthesis, structure and interconversion of two Co(II) coordination polymers showing topological isomerism from 1D chain to 3D chiral network" @default.
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- W2028235912 doi "https://doi.org/10.1016/s0277-5387(03)00455-8" @default.
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