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- W2028242107 abstract "Diaryloxytetraorganodistannoxanes, {[R2Sn(OAr)]2} (R = Me, Et, Pr, Bu; OAr = OPh, OC6H4Cl-2, OC6H4Me-2, OC6H4OMe-2, OC6H4OEt-2) have been prepared and characterized by IR and NMR (1H, 13C, 119Sn) spectroscopy. The compounds are assigned tetranuclear distannoxane structures in solution. The crystal structure of a representative compound, {[nBu2Sn(OC6H4OMe-2)]2O}2, has confirmed the spectroscopic assignments. The centrosymmetric molecule features a planar Sn2O2 unit with a nBu2Sn group connected to each bridging O atom. There are two independent OC6H4OMe-2 ligands in the structure, one bridges both the endo- and exo-cyclicl Sn atoms and the other is coordinated only to the exo-cyclic Sn atom; the result is that both Sn atoms are five-coordinate, and have distorted trigonal bipyramidal geometries." @default.
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- W2028242107 date "1991-11-01" @default.
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- W2028242107 title "Diaryloxytetraorganodistannoxanes: synthesis and characterization by IR and NMR (1H, 13C and 119Sn) spectroscopy. Crystal structure of {[nBu2Sn(OC6H4OMe-2)]2O}2" @default.
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- W2028242107 doi "https://doi.org/10.1016/0022-328x(91)80218-9" @default.
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