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- W2028245635 abstract "Isocyanid-Platin(II)-Komplexe trans-[Ph3P)2LPtCl]+Cl− (2) (L = vinyloges Aminoisonitril entstehen aus cis-Ph3P)2PtCl2 und L; sie werden als stabile PF-Salze (3) isoliert. Die Verbindungen 2 spalten beim Erhitzen Ph3P ab unter Bildung der neutralen Komplexe cis-(Ph3P)LPtCl2 (4), die sich mit Aminen HNR2R3 zu den Diaminocarben-Komplexen cis-(Ph3P)[R1HN)(R2R3 N)C]PtCl(amine)+Cl2 (7) umsetzen, wobei als Zwischenstufen ionische Verbindungen [(Ph3P)[R1HN)(R2R3N)C]PtCl(amin)] +PF (5) gefaßt wurden. Platinum(II) Complexes of Vinylogous Amino Isocyanides Isocyanide platinum(II) complexes trans-[(Ph3P)2LPtCl]+Cl− (2) (L = vinylogous aminoisonitrile are formed from cis-(Ph3P)2PtCl2 and L; the cations of 2 have been isolated as PF salts (3). At higher temperatures the salts 2 give the neutral complexes cis-(Ph3P)LPtCl2 (4) and PPh3. Treatment of 4 with amines HNR2R3 affords the diaminocarbene complexes cis-[(Ph3P)[(R1R3N)C]PtCl(amine)]+Cl− (isolated as PF salts 5) which on heating give the compounds cis-(Ph3P)[R1HN)(R2R3 N)C]PtCl2 (7)." @default.
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- W2028245635 date "1983-09-01" @default.
- W2028245635 modified "2023-10-09" @default.
- W2028245635 title "Platin(II)‐Komplexe von vinylogen Aminoisocyaniden" @default.
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- W2028245635 doi "https://doi.org/10.1002/cber.19831160918" @default.
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