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• W2028247206 abstract "Abstract Bubble-point pressures and vapour compositions of four binary vapour-liquid equilibrium systems are correlated in the normal and critical regions using two temperature-independent parameters. The method is based on a statistical mechanical formulation of the principle of corresponding states and van der Waals' two fluid approximation. A two parameter working equation for calculation of the equilibrium ratios is derived. The parameters are determined by fitting the working equation to pressure-temperature-composition data at one isotherm, and the obtained parameters are then used for the prediction of equilibrium ratios at all other temperatures and pressures of the system. Henry's law constants are also predicted in the critical region. The method is shown to work reasonably for the ArN 2 , CH 4 Ar, CH 4 CO, and ArCO systems." @default.
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• W2028247206 date "1973-01-01" @default.
• W2028247206 modified "2023-09-28" @default.
• W2028247206 title "Molecular thermodynamics of solutions in the normal and critical regions—III. Equilibrium ratios for the ArN2, CH4CO, ArCH4 and ArCO systems" @default.
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• W2028247206 doi "https://doi.org/10.1016/0300-9467(73)85018-x" @default.
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