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- W2028254849 abstract "Abstract The radical polymerization of tetraallyl ammonium chloride (TAAC) was carried out in water using azo‐initiator as compared to that of diallyl dimethyl ammonium chloride (DADMAC); the rate of polymerization was quite low for TAAC, around one‐third of DADMAC. Kinetic discussion revealed the importance of degradative chain transfer in the polymerization of TAAC. The cyclopolymerizability of TAAC was estimated kinetically as the ability of 5‐membered monocyclic radical to form a bicyclic ring, giving the cyclization constant of 21 mol/L at [M] = 2 mol/L. Gelation occurred at around 20% conversion." @default.
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- W2028254849 date "1989-05-01" @default.
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- W2028254849 title "Polymerization of tetraallyl ammonium chloride" @default.
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- W2028254849 doi "https://doi.org/10.1002/pola.1989.080270602" @default.
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