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• W2028260899 abstract "Reaction of Ru3(CO)12, with 2-(2'-pyridyl)benzimidazole (HPBI) resulted in the formation of Ru(CO)3(HPBI) (I) complex. In presence of pyridine or dipyridine, the two derivatives [Ru(CO)3(HPBI)].Py (II) and [Ru(CO)3(HPBI)].dpy (III) were isolated. The corresponding reactions of Os3(CO)12 yielded only one single product; Os(CO)2(HPBI)2 (IV). Spectroscopic studies of these complexes revealed intramolecular metal to ligand CT interactions. Reactions of RuCl3 with HPBI gave three distinct products; [Ru(HPBI)2Cl2]Cl (V), [Ru(HPBI)(dipy)Cl2]C1 (VI) and [Ru(PBI)2(py)2]Cl (VII). The UV-vis studies indicated the presence of intramolecular ligand to metal CT interactions. Electrochemical investigation of the complexes showed some irreversible, reversible and quasi-reversible redox reactions due to tautomeric interconversions through electron transfer." @default.
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• W2028260899 date "2001-04-01" @default.
• W2028260899 modified "2023-10-14" @default.
• W2028260899 title "Spectro- and electrochemical studies of some ruthenium and osmium complexes of 2-(2′-pyridyl)benzimidazole; complexes with intra-molecular charge transfer" @default.
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• W2028260899 doi "https://doi.org/10.1016/s1386-1425(00)00411-x" @default.
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