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- W2028276695 abstract "Metal-containing ZSM-5 (MZSM-5) molecular sieves were prepared and characterized by XRD, EDX, SEM and N2-physisorption. The prepared MZSM-5 catalysts were found to be very effective for cyclohexane oxidation with tert-butyl-hydroperoxide in ionic liquid [emim]BF4 under mild conditions. Good yields and high selectivity of products were found in the ionic liquid compared within molecular solvent. The catalytic activity of FeZSM-5 was superior to that of other MZSM-5 and the as-received HZSM-5 in ionic liquid. For cyclohexane oxidation catalyzed by FeZSM-5, 20.9% conversion of cyclohexane and 98.2% selectivity of desired products were obtained in ionic liquid at the temperature of 90 °C. The catalyst/ionic liquid system could be successfully recycled by a simple decantation procedure without significant loss of activity." @default.
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- W2028276695 date "2008-01-18" @default.
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- W2028276695 title "Oxidation of cyclohexane catalyzed by metal-containing ZSM-5 in ionic liquid" @default.
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- W2028276695 doi "https://doi.org/10.1016/j.molcata.2007.10.030" @default.
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