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• W2028284025 endingPage "6568" @default.
• W2028284025 startingPage "6564" @default.
• W2028284025 abstract "Propargyl 1,2-orthoesters are identified as glycosyl donors. Various glycosides and disaccharides were synthesized in a stereoselective manner using AuBr3 as the promoter. AuBr3 may activate the alkyne resulting in the formation of a 1,2-dioxolenium ion and also behaves as a Lewis acid to facilitate the attack of the glycosyl acceptor. The versatility of the protocol was demonstrated using a panel of aglycones comprising aliphatic, alicyclic, steroidal and sugar alcohols." @default.
• W2028284025 created "2016-06-24" @default.
• W2028284025 creator A5031872284 @default.
• W2028284025 creator A5087914112 @default.
• W2028284025 date "2007-09-01" @default.
• W2028284025 modified "2023-10-16" @default.
• W2028284025 title "Propargyl 1,2-orthoesters as glycosyl donors: stereoselective synthesis of 1,2-trans glycosides and disaccharides" @default.
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• W2028284025 doi "https://doi.org/10.1016/j.tetlet.2007.07.015" @default.
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