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- W2028294204 abstract "The interactions of free base porphyrins with tetracyanoethylene and 2,3-dichloro-5,6-dicyanobezoquinone as acceptors result in charge-transfer adducts of composition 2:1 of acceptor to donor, [(acceptor)2(donor)]. Formation constants, K, as well as the thermodynamic parameters, ΔH°, ΔS°, and ΔG° were determined by UV-Vis titration method for the adducts. Surprisingly, the values of DSº ñ 0 and DHº ñ 0 for TCNE are in contrast to ΔH° á 0 and ΔS° á 0 for DDQ. Negative values of DGº make these interactions favorable in the both cases.KEY WORDS: DDQ, TCNE, Free base porphyrin, Thermodynamic properties Bull. Chem. Soc. Ethiop. 2011, 25(1), 127-136." @default.
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- W2028294204 date "2011-02-03" @default.
- W2028294204 modified "2023-10-17" @default.
- W2028294204 title "<b>Comparison of acceptor properties for interaction of TCNE and DDQ with some free base porphyrins</b>" @default.
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- W2028294204 doi "https://doi.org/10.4314/bcse.v25i1.63376" @default.
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