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- W2028296003 abstract "Liquid phase oxidation of glycerol under basic conditions was examined for a series of Au–Pd/C bimetallic catalysts prepared by electroless deposition. Enhanced activity was observed for bimetallic compositions with θAu > 0.30, with a maximum in activity at θAu = 0.50 having a turnover frequency ∼20 times larger than for Pd and ∼4 times larger than for gold. A volcano shaped curve suggests the formation of bimetallic sites composed of Au–Pd in close contact, with the maximum at θAu = 0.50 indicating the largest concentration of bimetallic sites at that coverage. Further increase in the coverage of Au on Pd lead to a catalytic surface approaching that of monometallic Au with lower TOF values. Selectivity to glyceric acid was 80% (±2%) for Pd and Au–Pd bimetallic catalysts below θAu < 0.90. Selectivity to glycerate remained constant as long as there are sufficient Pd sites to rapidly decompose the non-selective H2O2 oxidant that is presumably produced on the Au sites. At the highest Au coverages, selectivity dropped to <60% due to further oxidation of glycerate to C1 and C2 oxygenated products." @default.
- W2028296003 created "2016-06-24" @default.
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- W2028296003 date "2014-04-01" @default.
- W2028296003 modified "2023-09-26" @default.
- W2028296003 title "Selective liquid-phase oxidation of glycerol over Au–Pd/C bimetallic catalysts prepared by electroless deposition" @default.
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- W2028296003 doi "https://doi.org/10.1016/j.apcata.2014.01.011" @default.
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