FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2028313820> ?p ?o ?g. }

• W2028313820 endingPage "248" @default.
• W2028313820 startingPage "233" @default.
• W2028313820 abstract "The influence of the organic modifiers methanol (MeOH), acetonitrile (AN) and tetrahydrofuran (THF) on polar group selectivity in reversed-phase liquid chromatography has been studied. In order to elucidate polar group effects, we have first explored the influence of the surface coverage of bonded phase on selectivity. Using a series of synthesized n-octy bonded phases, we have been able to observe significant differences in group contribution with bonded phase coverage, the largest differences arising from MeOHH2O as mobile phase and the least from THFH2O as mobile phase. The importance of using phases that minimize accessible silanol groups in order to study the influence of the mobile phase has been emphasized. We have selected a high coverage n-octyl phase that is silanized for these studies. In order to examine polar group effects, we have normalized the methylene group increment in the MeOHH2O, ANH2O and THH2O binary phases. As the hydrophobic selectivity is thus roughly normalized, meaningful relative polar group contributions are observed. Plots of logk′ (THFH2O) vs. log k′ (MeOHH2O) reveal particularly striking polar group differences. The practical usefulness of the plots is shown in the peak reversal of solute mixtures with the two mobile phases. Further studies reveal that polar group selectivity can be powerfully controlled using ternary phases of MeOHTHFH2O. Thus, the choice of mobile phase can greatly influence separation in reversed-phase liquid chromatography." @default.
• W2028313820 created "2016-06-24" @default.
• W2028313820 creator A5020025505 @default.
• W2028313820 creator A5065682109 @default.
• W2028313820 creator A5091570092 @default.
• W2028313820 date "1978-10-01" @default.
• W2028313820 modified "2023-09-23" @default.
• W2028313820 title "The role of organic modifiers on polar group selectivity in reversed-phase liquid chromatography" @default.
• W2028313820 cites W1479682365 @default.
• W2028313820 cites W1573248480 @default.
• W2028313820 cites W1977052721 @default.
• W2028313820 cites W1995633020 @default.
• W2028313820 cites W1996457760 @default.
• W2028313820 cites W2000911040 @default.
• W2028313820 cites W2005119288 @default.
• W2028313820 cites W2011058847 @default.
• W2028313820 cites W2013241826 @default.
• W2028313820 cites W2026824633 @default.
• W2028313820 cites W2032220672 @default.
• W2028313820 cites W2039108355 @default.
• W2028313820 cites W2043540882 @default.
• W2028313820 cites W2046654815 @default.
• W2028313820 cites W2050199810 @default.
• W2028313820 cites W2057628626 @default.
• W2028313820 cites W2068542625 @default.
• W2028313820 cites W2070893400 @default.
• W2028313820 cites W2071158076 @default.
• W2028313820 cites W2076659673 @default.
• W2028313820 cites W2086971082 @default.
• W2028313820 cites W2088023573 @default.
• W2028313820 cites W2317261051 @default.
• W2028313820 cites W2326727681 @default.
• W2028313820 cites W2330906140 @default.
• W2028313820 cites W2333079398 @default.
• W2028313820 doi "https://doi.org/10.1016/s0021-9673(00)89970-7" @default.
• W2028313820 hasPublicationYear "1978" @default.
• W2028313820 type Work @default.
• W2028313820 sameAs 2028313820 @default.
• W2028313820 citedByCount "221" @default.
• W2028313820 countsByYear W20283138202012 @default.
• W2028313820 countsByYear W20283138202013 @default.
• W2028313820 countsByYear W20283138202015 @default.
• W2028313820 countsByYear W20283138202017 @default.
• W2028313820 countsByYear W20283138202018 @default.
• W2028313820 countsByYear W20283138202019 @default.
• W2028313820 countsByYear W20283138202020 @default.
• W2028313820 countsByYear W20283138202022 @default.
• W2028313820 countsByYear W20283138202023 @default.
• W2028313820 crossrefType "journal-article" @default.
• W2028313820 hasAuthorship W2028313820A5020025505 @default.
• W2028313820 hasAuthorship W2028313820A5065682109 @default.
• W2028313820 hasAuthorship W2028313820A5091570092 @default.
• W2028313820 hasConcept C113196181 @default.
• W2028313820 hasConcept C116817701 @default.
• W2028313820 hasConcept C118792377 @default.
• W2028313820 hasConcept C121332964 @default.
• W2028313820 hasConcept C1276947 @default.
• W2028313820 hasConcept C161790260 @default.
• W2028313820 hasConcept C178790620 @default.
• W2028313820 hasConcept C179998833 @default.
• W2028313820 hasConcept C185592680 @default.
• W2028313820 hasConcept C199360897 @default.
• W2028313820 hasConcept C203147553 @default.
• W2028313820 hasConcept C2776701986 @default.
• W2028313820 hasConcept C2777463227 @default.
• W2028313820 hasConcept C2777581007 @default.
• W2028313820 hasConcept C2780471494 @default.
• W2028313820 hasConcept C29705727 @default.
• W2028313820 hasConcept C41008148 @default.
• W2028313820 hasConcept C43617362 @default.
• W2028313820 hasConcept C44280652 @default.
• W2028313820 hasConcept C45188465 @default.
• W2028313820 hasConcept C64452783 @default.
• W2028313820 hasConceptScore W2028313820C113196181 @default.
• W2028313820 hasConceptScore W2028313820C116817701 @default.
• W2028313820 hasConceptScore W2028313820C118792377 @default.
• W2028313820 hasConceptScore W2028313820C121332964 @default.
• W2028313820 hasConceptScore W2028313820C1276947 @default.
• W2028313820 hasConceptScore W2028313820C161790260 @default.
• W2028313820 hasConceptScore W2028313820C178790620 @default.
• W2028313820 hasConceptScore W2028313820C179998833 @default.
• W2028313820 hasConceptScore W2028313820C185592680 @default.
• W2028313820 hasConceptScore W2028313820C199360897 @default.
• W2028313820 hasConceptScore W2028313820C203147553 @default.
• W2028313820 hasConceptScore W2028313820C2776701986 @default.
• W2028313820 hasConceptScore W2028313820C2777463227 @default.
• W2028313820 hasConceptScore W2028313820C2777581007 @default.
• W2028313820 hasConceptScore W2028313820C2780471494 @default.
• W2028313820 hasConceptScore W2028313820C29705727 @default.
• W2028313820 hasConceptScore W2028313820C41008148 @default.
• W2028313820 hasConceptScore W2028313820C43617362 @default.
• W2028313820 hasConceptScore W2028313820C44280652 @default.
• W2028313820 hasConceptScore W2028313820C45188465 @default.
• W2028313820 hasConceptScore W2028313820C64452783 @default.
• W2028313820 hasLocation W20283138201 @default.
• W2028313820 hasOpenAccess W2028313820 @default.
• W2028313820 hasPrimaryLocation W20283138201 @default.
• W2028313820 hasRelatedWork W1466923503 @default.

• next