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- W2028339905 abstract "The effect of the anharmonic interaction on the spin-lattice relaxation rates has been studied theoretically for ${mathrm{Cr}}^{3+}$ and ${mathrm{Ni}}^{2+}$ ions in a MgO crystal. The modification of the relaxation rates due to the anharmonic interaction has been calculated using the Debye model of phonons and an effective-point-charge model for the ligands. The enhancement of the relaxation rate is shown to depend on the paramagnetic ion under consideration. $frac{1}{{T}_{1}}$ is enhanced by an order of magnitude for the case of ${mathrm{Cr}}^{3+}$ ion, whereas there is hardly any change for ${mathrm{Ni}}^{2+}$ ion. This is principally due to the fact that the ratio of spin-phonon-coupling parameters for the direct process to those for the Raman process is smaller in the case of MgO: ${mathrm{Ni}}^{2+}$ than in the case of MgO: ${mathrm{Cr}}^{3+}$." @default.
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- W2028339905 date "1972-09-01" @default.
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- W2028339905 title "Effect of the Anharmonic Interactions on the Spin-Lattice Relaxation of Paramagnetic Ions in a MgO Crystal" @default.
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