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- W2028339992 abstract "Silicon Compounds with Strong Intramolecular Steric Interactions, 36. — A Bicyclic Disilane from the Reaction of 1,2-Dichlorotetramesityldisilane with Lithium tert-Butylamide Treatment of 1,2-dichlorotetramesityldisilane (1) with lithium tert-butylamide gives the 4b,9b-disilaindeno[2,1-a]indene derivative 3 whose NMR spectra in solution show a hindered rotation about the SiC(mesityl) bonds even at high temperatures. The X-ray structure analysis of 3 reveals a strong folding of the two halves of the bicyclic molecule and a considerably short SiSi bond length of 230.7 pm." @default.
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- W2028339992 date "1989-08-01" @default.
- W2028339992 modified "2023-10-14" @default.
- W2028339992 title "Siliciumverbindungen mit starken intramolekularen sterischen Wechselwirkungen, 36: Ein bicyclisches Disilan aus der Umsetzung von 1,2-Dichlortetramesityldisilan mit Lithium-tert-butylamid" @default.
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- W2028339992 doi "https://doi.org/10.1002/cber.19891220818" @default.
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