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- W2028349143 abstract "An easy and versatile functionalization of (η5-cyclohexadienyl)Mn(CO)3 complexes by a lithiation/electrophilic quench sequence is described. Using TMSCl as a model electrophile, the reactivity of the series of substrates 1–5 was studied. In addition to the regiochemistry control by ortho-directing groups, such as OMe or Cl, the results suggest a strong influence of the Mn(CO)3 tripod conformation on the regioselectivity of the lithiation. In order to gain a better understanding of the reactivity features of the cyclohexadienyl ligand in the η5 complex, a theoretical investigation was undertaken. It indicates that the regioselectivity relies mainly on the intrinsic stabilities of the deprotonated intermediates, the species lithiated at C2, eclipsed by a Mn−CO bond, being the most stable one. The synthetic methodology was finally successfully extended to a representative range of electrophiles, giving access in good to excellent yields to η5 derivatives substituted by various heteroatoms (iodine, sulfur, or stannyl groups) or functions, such as ketone, ester, amide, or alcohols, α to the π system." @default.
- W2028349143 created "2016-06-24" @default.
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- W2028349143 date "2008-01-23" @default.
- W2028349143 modified "2023-10-18" @default.
- W2028349143 title "A Combined Experimental−Theoretical Study on the Lithiation/Electrophilic Quench Sequence of (η<sup>5</sup>-Cyclohexadienyl)Mn(CO)<sub>3</sub> Complexes" @default.
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- W2028349143 doi "https://doi.org/10.1021/om7010529" @default.
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