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• W2028351703 abstract "Ammonium azide (NH4N3) has been studied by in situ high-pressure X-ray diffraction and Raman scattering at room temperature. NH4N3 exhibits strong hydrogen bonding features with compression. The hydrogen bond weaken with increasing pressure due to the bending of N−H…N bond, leading to the increase of N−H stretch frequency and rotation of azide anions at 2b and 4h Wyckoff positions up to 2.9 GPa. The orientation of azide anions obviously influences the compressibility properties of NH4N3. The phase transition involves rotation of azide anions and a proximity of a and c, temporally assigned as a reversible second-order orthorhombic-to-tetragonal transition." @default.
• W2028351703 created "2016-06-24" @default.
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• W2028351703 creator A5057209439 @default.
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• W2028351703 date "2013-03-25" @default.
• W2028351703 modified "2023-10-16" @default.
• W2028351703 title "High pressure synchrotron x-ray diffraction and Raman scattering studies of ammonium azide" @default.
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• W2028351703 doi "https://doi.org/10.1063/1.4798336" @default.
• W2028351703 hasPublicationYear "2013" @default.
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