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• W2028354673 endingPage "146" @default.
• W2028354673 startingPage "142" @default.
• W2028354673 abstract "The crystal structures and magnetic properties of four μ-(1,5) singly bridging dicyanamide complexes, specifically Mn{N(CN)2}2(DMSO)2 (1), Fe{N(CN)2}2(DMSO)2 (2), Co{N(CN)2}2(DMSO)2 (3), and Ni{N(CN)2}2(DMSO)2 (4), (DMSO = dimethyl sulfoxide) are presented. The compounds are isostructural, in which the MII ions adopt a distorted octahedral geometry, coordinating to four nitrile N atoms of the dicyanamide ligand and to the two DMSO molecules, giving rise to (4,4) pseudo-2D square grid sheets. Magnetic interactions in these materials are via the five atom dicyanamide bridge [NCNCN], which is known to propagate weak magnetic exchange, and the complexes do not undergo long-range ordering down to 2 K. Single crystal X-ray diffraction, FTIR spectroscopy, CHN analyses, and SQUID magnetometry were used to characterize these materials." @default.
• W2028354673 created "2016-06-24" @default.
• W2028354673 creator A5057815327 @default.
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• W2028354673 date "2013-12-01" @default.
• W2028354673 modified "2023-10-16" @default.
• W2028354673 title "Structural and magnetic properties of four layered dicyanamide-based coordination polymers: M{N(CN)2}2(DMSO)2, [M=Mn, Fe, Co, Ni]" @default.
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• W2028354673 doi "https://doi.org/10.1016/j.poly.2013.03.017" @default.
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