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- W2028356410 abstract "Herein we disclose an organocatalytic aryl–aryl bond-forming process for the regio- and atroposelective synthesis of 2,2′-diamino-1,1′-binaphthalenes (BINAMs). In the presence of catalytic amounts of axially chiral phosphoric acids, achiral N,N′-binaphthyl hydrazines undergo a facile [3,3]-sigmatropic rearrangement to afford enantiomerically enriched BINAM derivatives in good to excellent yield. This transformation represents the first example of a metal-free, catalytic C(sp2)–C(sp2) bond formation between two aromatic rings with concomitant de novo atroposelective installation of an axis of chirality. Density functional calculations reveal that, in the transition state for C–C bond formation, the phosphoric acid proton of the catalyst is fully transferred to one of the N-atoms of the substrate, and the resulting phosphate acts as a chiral counterion." @default.
- W2028356410 created "2016-06-24" @default.
- W2028356410 creator A5003746558 @default.
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- W2028356410 date "2013-05-09" @default.
- W2028356410 modified "2023-10-17" @default.
- W2028356410 title "Organocatalytic Aryl–Aryl Bond Formation: An Atroposelective [3,3]-Rearrangement Approach to BINAM Derivatives" @default.
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- W2028356410 doi "https://doi.org/10.1021/ja401709k" @default.
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