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- W2028368498 abstract "ABSTRACT The chromatographic separation of enantiomers of a series of 2-alkoxysubstituted esters of phenylcarbamic acid (C1−C10) were studied on (β- and γ-) cyclodextrin chiral stationary phases. The pH and concentration of organic modifier in the mobile phase were optimized. It was observed that the chromatographic performance of basic compounds could be strongly enhanced by increasing the pH of the mobile phase. Increasing the pH produced higher values for the enantiomeric resolution and the retention factors. This work demonstrated that the nonpolar interactions between the chiral stationary phase and the neutral molecules of these enantiomers had the greatest effect on enantioresolution. Acknowledgments" @default.
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- W2028368498 date "2002-08-19" @default.
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- W2028368498 title "STUDY OF MECHANISM OF ENANTIOSEPARATION. II. HPLC CHIRAL ANALYSIS OF ALKOXYSUBSTITUTED ESTERS OF PHENYLCARBAMIC ACID" @default.
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